Some high-energy trinitromethyl-ONN-furazans as binder plasticizers in model solid composite propellants

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To identify promising areas for the search for high-energy materials, a comprehensive analysis of the energy potential of compounds of various classes is an urgent need. This work is devoted to the study of the energy potential of some organic compounds containing the –N=N(O)–C(NO2)3 fragment in their structure as plasticizers of a polymeric binder in solid composite propellants. Nine trinitromethyl-ONN-azoxy-derivatives of furazan and one similar methane compound were studied, four of which are actually synthesized substances, the rest are still hypothetical structures. The ballistic efficiency of solid composite propellants of three different types (without metal, with aluminum and with aluminum hydride), in which one of the studied compounds with a trinitromethyl-ONN-azoxy fragment acts as a plasticizer of the polymer binder, the values of the enthalpy of formation and density of which were determined by the calculated way, and a comparison of the ballistic efficiency of such propellants with similar compositions containing the most powerful of the currently considered energy-intensive components as a plasticizer: nitroglycerin, tetranitromethane, or dinitrofurazan. It has been shown that practically all the studied representatives of the class of trinitromethyl-ONN-diazene oxides are significantly superior in terms of ballistic efficiency to the reference plasticizers.

作者简介

V. Parakhin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
俄罗斯联邦, Moscow

V. Volokhov

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka

E. Amosova

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka

I. Akostelov

Lomonosov Moscow State University

Email: lempert@icp.ac.ru
俄罗斯联邦, Moscow

D. Lempert

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

编辑信件的主要联系方式.
Email: lempert@icp.ac.ru
俄罗斯联邦, Chernogolovka

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