Some high-energy trinitromethyl-ONN-furazans as binder plasticizers in model solid composite propellants

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Abstract

To identify promising areas for the search for high-energy materials, a comprehensive analysis of the energy potential of compounds of various classes is an urgent need. This work is devoted to the study of the energy potential of some organic compounds containing the –N=N(O)–C(NO2)3 fragment in their structure as plasticizers of a polymeric binder in solid composite propellants. Nine trinitromethyl-ONN-azoxy-derivatives of furazan and one similar methane compound were studied, four of which are actually synthesized substances, the rest are still hypothetical structures. The ballistic efficiency of solid composite propellants of three different types (without metal, with aluminum and with aluminum hydride), in which one of the studied compounds with a trinitromethyl-ONN-azoxy fragment acts as a plasticizer of the polymer binder, the values of the enthalpy of formation and density of which were determined by the calculated way, and a comparison of the ballistic efficiency of such propellants with similar compositions containing the most powerful of the currently considered energy-intensive components as a plasticizer: nitroglycerin, tetranitromethane, or dinitrofurazan. It has been shown that practically all the studied representatives of the class of trinitromethyl-ONN-diazene oxides are significantly superior in terms of ballistic efficiency to the reference plasticizers.

About the authors

V. V. Parakhin

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences

Email: lempert@icp.ac.ru
Russian Federation, Moscow

V. M. Volokhov

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

Email: lempert@icp.ac.ru
Russian Federation, Chernogolovka

E. S. Amosova

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

Email: lempert@icp.ac.ru
Russian Federation, Chernogolovka

I. I. Akostelov

Lomonosov Moscow State University

Email: lempert@icp.ac.ru
Russian Federation, Moscow

D. B. Lempert

Zelinsky Institute of Organic Chemistry Russian Academy of Sciences

Author for correspondence.
Email: lempert@icp.ac.ru
Russian Federation, Chernogolovka

References

  1. Lempert D.B., Nechiporenko G.N., Soglasnova S.I. // Khim. Fiz. 1999. V. 18. P. 86.
  2. Lempert D.B., Nechiporenko G.N., Soglasnova S.I. // Comb. Explos. Shock Waves. 2009. V. 45. P. 160. https://doi.org/10.1007/s10573-009-0021-9
  3. Lempert D., Kazakov A., Sheremetev A. // Mendeleev Commun. 2022. V. 32. P. 601. https://doi.org/10.1016/j.mencom.2022.09.010
  4. Luk’yanov O.A., Salamonov Y.B., Struchkov Y.T., Burtsev Y.N., Kuz’min V.S. // Mendeleev Commun. 1992. V. 2. P. 52. https://doi.org/10.1070/MC1992v002n02ABEH000127.
  5. Luk’yanov O.A., Pokhvisneva G.V., Ternikova T.V., Shlykova N.I., Salamonov Yu.B. // Russ. Chem. Bull. 2009. V. 58. P. 2063. https://doi.org/10.1007/s11172-009-0283-0
  6. Luk’yanov O.A., Pokhvisneva G.V., Ternikova T.V., Shlykova N.I., Shagayeva M.E. // Russ. Chem. Bull. 2011. V. 60. P. 1703. https://doi.org/10.1007/s11172-011-0254-0
  7. Luk’yanov O.A., Parakhin V.V., Pokhvisneva G.V., Ternikova T.V. // Russ. Chem. Bull. 2012. V. 61. P. 355. https://doi.org/10.1007/s11172-012-0049-y
  8. Luk’yanov O.A., Pokhvisneva G.V., Ternikova T.V., Shlykova N.I. // Russ. Chem. Bull. 2012. V. 61. P. 360. https://doi.org/10.1007/s11172-012-0050-5
  9. Luk’yanov O.A., Parakhin V.V. // Russ. Chem. Bull. 2012. V. 61. P. 1582. https://doi.org/10.1007/s11172-012-0210-7
  10. Luk’yanov O.A., Pokhvisneva G.V., Ternikova T.V.// Russ. Chem. Bull. 2012. V. 61. P. 1783. https://doi.org/10.1007/s11172-012-0245-9
  11. Parakhin V.V., Luk’yanov O.A. // Russ. Chem. Bull. 2013. V. 62. P. 516. https://doi.org/10.1007/s11172-013-0071-8
  12. Parakhin V.V., Luk’yanov O.A. // Russ. Chem. Bull. 2013, V. 62. P. 2007. https://doi.org/10.1007/s11172-013-0291-y
  13. Luk’yanov O.A., Pokhvisneva G.V., Ternikova T.V., Shlykova N.I. // Russ. Chem. Bull. 2015. V. 64. P. 83. https://doi.org/10.1007/s11172-015-0824-7D
  14. Luk’yanov O.A., Pokhvisneva G.V., Ternikova T.V., Shlykova N.I. // Russ. Chem. Bull. 2015. V. 64. P. 137. https://doi.org/10.1007/s11172-015-0832-7
  15. Zhang J., Bi F., Lian P., Zhang J., Wang B. // Chin. J. Org. Chem. 2017. V. 37. P. 2736. https://doi.org/10.6023/cjoc201701014
  16. Luk’yanov O.A., Parakhin V.V. 3-(trinitromethyl-ONN-azoxy)-4-nitraminofurazans and methods for production thereof. Patent of Russian Federation 2455108. 2013.
  17. Lempert D.B., Nechiporenko G.N., Manelis G.B. // Cent. Eur. J. Energ. Mater. 2006. V. 3. P. 73.
  18. Trusov B.G. // XIV International Symposium on Chemical Thermodynamics. St. Petersburg. 2002. P. 483.
  19. Gudkova I.Yu., Zyuzin I.N., Lempert D.B. // Russ. J. Phys. Chem. B. 2022. V. 16. P. 58. https://doi.org/10.1134/S1990793122010067
  20. Zyuzin I.N., Gudkova I.Yu., Lempert D.B. // Russ. J. Phys. Chem. B. 2020. V. 14. P. 804. https://doi.org/10.1134/S1990793120050140
  21. Zyuzin I.N., Gudkova I.Yu., Lempert D.B. // Russ. J. Phys. Chem. B. 2021. V. 15. P. 611. https://doi.org/10.1134/S1990793121040138
  22. Zyuzin I.N., Gudkova I.Yu., Lempert D.B. // Russ. J. Phys. Chem. B. 2022. V. 16. P. 902. https://doi.org/10.1134/S1990793122050141
  23. Zyuzin I.N., Gudkova I.Yu., Lempert D.B. // Russ. J. Phys. Chem. B. 2022. V. 16. P. 902. https://doi.org/10.1134/S1990793122050141
  24. Pavlovets G.Ya., Tsutsuran V.I. Physical and Chemical Properties of Gunpowders and Rocket Propellants. Moscow: Minist. Oborony, 2009 [in Russian].
  25. Westwell M.S., Searle M.S., Wales D.J., Williams D. // J. Am. Chem. Soc. 1995. V. 117. P. 5013. https://doi.org/10.1021/ja00123a001
  26. Kotomin A.A., Kozlov A.S. Density of organic compounds. Calculation of density from contributions of molecular fragments. Saint-Petersburg: St. Petersburg State Technological Institute (Technical University), 2005 [in Russian].
  27. Voevodin V.V., Antonov A.S., Nikitenko D.A. et al. // Supercomput. Front. Innov. 2019. V. 6. № 2. P. 4. https://doi.org/10.14529/jsfi190201
  28. Voevodin V., Zhumatiy S., Sobolev S. et al. // Otkrytye sistemy. SUBD [in Russian]. 2012. V. 7. P. 36.
  29. Nikitenko D., Voevodin V., Zhumatiy S. // Supercomput. Front. Innov. 2018. V. 5. № 2. P. 4. https://doi.org/10.14529/jsfi180201

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