Enviar artigo por via de e-mail Influence of self-heating on the kinetics of an exothermal reaction under isothermal conditions
- Autores: Korsunskiy B.L.1,2, Samoilenko N.G.1
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Afiliações:
- Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Russian Academy of Sciences
- N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences
- Edição: Volume 43, Nº 1 (2024)
- Páginas: 47-51
- Seção: Kinetics and mechanism of chemical reactions, catalysis
- URL: https://cijournal.ru/0207-401X/article/view/674997
- DOI: https://doi.org/10.31857/S0207401X24010066
- EDN: https://elibrary.ru/mjdeev
- ID: 674997
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Resumo
Estimates have been made showing that when an exothermal reaction proceeds in an isothermal medium (in a thermostat), self-heating occurs, the values of which are determined by the competition between the processes of heat input and heat removal. Relationships are obtained that make it possible to estimate the deviation of the observed values of the kinetic parameters from the true values and to reveal the influence of various parameters on these deviations.
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Sobre autores
B. Korsunskiy
Federal Research Center of Problems of Chemical Physics and Medicinal ChemistryRussian Academy of Sciences; N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences
Email: n.g.samoilenko@mail.ru
Rússia, Chernogolovka; Moscow
N. Samoilenko
Federal Research Center of Problems of Chemical Physics and Medicinal ChemistryRussian Academy of Sciences
Autor responsável pela correspondência
Email: n.g.samoilenko@mail.ru
Rússia, Chernogolovka
Bibliografia
- N. G. Samoilenko, A. A. Vinokurov, V. G. Abramov, A. G. Merzhanov, Zhurnal fiz. khimii 44(1), 39 (1970) [in Russian].
- A. I. Serbinov, Doklady akademii nauk SSSR 129(3), 627 (1959) (in Russian).
- A. I. Serbinov, Zhurnal fiz. khimii 33(12), 2641 (1970) (in Russian).
- D. A. Frank-Kamenetskii, Diffusion and Heat Exchange in Chemical Kinetics (Nauka, Moscow, 1987; Springer, Heidelberg, 1995).
- R. Meyer, J. Kohler, A. Homburg, Explosives. (Wiley-VCH, 2002. 474 p.).
- G. B. Manelis, G. M. Nazin, Yu.I. Rubtsov, V.A. Strunin. Thermal Decomposition and Combustion of Explosives and Propellants G. B. Manelis, s. (Taylor and Francis Croup. L.-N.Y. 2003. 362 p.)
- S. S. Kutateladze, V. M. Borishanskiy. Spravochnik po teploperedache. (Gosudarstvennoye izdatel’stvo energeticheskoy literatury. L.-М. 1958. 414 p.) (in Russian).
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