电邮这篇文章 Influence of self-heating on the kinetics of an exothermal reaction under isothermal conditions
- 作者: Korsunskiy B.L.1,2, Samoilenko N.G.1
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隶属关系:
- Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Russian Academy of Sciences
- N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences
- 期: 卷 43, 编号 1 (2024)
- 页面: 47-51
- 栏目: Kinetics and mechanism of chemical reactions, catalysis
- URL: https://cijournal.ru/0207-401X/article/view/674997
- DOI: https://doi.org/10.31857/S0207401X24010066
- EDN: https://elibrary.ru/mjdeev
- ID: 674997
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详细
Estimates have been made showing that when an exothermal reaction proceeds in an isothermal medium (in a thermostat), self-heating occurs, the values of which are determined by the competition between the processes of heat input and heat removal. Relationships are obtained that make it possible to estimate the deviation of the observed values of the kinetic parameters from the true values and to reveal the influence of various parameters on these deviations.
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作者简介
B. Korsunskiy
Federal Research Center of Problems of Chemical Physics and Medicinal ChemistryRussian Academy of Sciences; N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences
Email: n.g.samoilenko@mail.ru
俄罗斯联邦, Chernogolovka; Moscow
N. Samoilenko
Federal Research Center of Problems of Chemical Physics and Medicinal ChemistryRussian Academy of Sciences
编辑信件的主要联系方式.
Email: n.g.samoilenko@mail.ru
俄罗斯联邦, Chernogolovka
参考
- N. G. Samoilenko, A. A. Vinokurov, V. G. Abramov, A. G. Merzhanov, Zhurnal fiz. khimii 44(1), 39 (1970) [in Russian].
- A. I. Serbinov, Doklady akademii nauk SSSR 129(3), 627 (1959) (in Russian).
- A. I. Serbinov, Zhurnal fiz. khimii 33(12), 2641 (1970) (in Russian).
- D. A. Frank-Kamenetskii, Diffusion and Heat Exchange in Chemical Kinetics (Nauka, Moscow, 1987; Springer, Heidelberg, 1995).
- R. Meyer, J. Kohler, A. Homburg, Explosives. (Wiley-VCH, 2002. 474 p.).
- G. B. Manelis, G. M. Nazin, Yu.I. Rubtsov, V.A. Strunin. Thermal Decomposition and Combustion of Explosives and Propellants G. B. Manelis, s. (Taylor and Francis Croup. L.-N.Y. 2003. 362 p.)
- S. S. Kutateladze, V. M. Borishanskiy. Spravochnik po teploperedache. (Gosudarstvennoye izdatel’stvo energeticheskoy literatury. L.-М. 1958. 414 p.) (in Russian).
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