UNCONVENTIONAL APPROACH FOR THE SYNTHESIS OF NICKEL AND PLATINUM COMPLEXES OF 1,3,6-AZADIPHOSPHACYCLOHEPTANES

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Resumo

The approach to the synthesis of bis-phospninesulfides and nickel and platinum chelate complexes of 1,3,6-azadiphosphacycloheptanes is supposed. The approach is based on the ability of 14-membered 1,8-diaza-3,6,10,13-tetraphosphacyclotetradecanes undergo the reversible transformation to the mixture of meso- and rac-isomers of 7-membered bisphosphines during the solution. The reaction of 1,8-diaza-3,6,10,13-tetra-phosphacyclotetradecanes with elementary sulfur results in 14-membered tetra(phosphinesulfides) or 7‑membered bis(phosphinesulfides) that depends on the reaction conditions. The reaction of 1,3,6-azadiphosphacycloheptanes, forming by the reversible dissociation of 14-membered tetraphosphines in chloroform, with Ni(CH3CN)6(BF4)2 and Pt(COD)Cl2 give corresponding chelate complexes. The structures of meso-isomer of 1-cyclohexyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptan-3,6-disulfide 8, bis-(κ2-1-isopropyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane)nickel bis(tetrafluoroborate) 9, bis-(κ2-1-icyclohexyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane)chloronickel tetrafluoroborate 10 and cis-dichloro-(κ2-1-cyclohexyl-3,6-diphenyl-1-aza-3,6-diphosphacycloheptane)-platinum(II) 13 were established by single crystal XRD analysis.

Sobre autores

E. Musina

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Autor responsável pela correspondência
Email: elli@iopc.ru
Russian Federation, 420088, Kazan

I. Strelnik

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: elli@iopc.ru
Russian Federation, 420088, Kazan

I. Litvinov

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: elli@iopc.ru
Russian Federation, 420088, Kazan

A. Karasik

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

Email: elli@iopc.ru
Russian Federation, 420088, Kazan

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Declaração de direitos autorais © Э.И. Мусина, И.Д. Стрельник, И.А. Литвинов, А.А. Карасик, 2023