TRANSFORMATIONS OF 5-HYDRAZINYL-1,2,4-TRIAZINES IN THE REACTION WITH 2,5-NORBORNADIENE

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Abstract

The interaction between 5-hydrazinyl-substituted 1,2,4-triazines and 2,5-norbornadiene at elevated temperature and pressure (in autoclave) have been studied. The 2-aminopyridines, 5-amino-1,2,4-triazines and 6-unsubstituted pyridines are the products of this reaction. The formation of last two products depends on the substituent at C3 position of the triazine.

About the authors

A. P. Krinochkin

Ural Federal University; I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620219, Yekaterinburg

A. Rammohan

Ural Federal University

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg

D. S. Kopchuk

Ural Federal University; I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620219, Yekaterinburg

I. L. Nikonov

Ural Federal University; I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Author for correspondence.
Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620219, Yekaterinburg

E. S. Starnovskaya

Ural Federal University; I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620219, Yekaterinburg

E. R. Sharafieva

Ural Federal University; Ural State Medical University, Ministry of Healthcare of the Russian Federation

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620028, Yekaterinburg

I. S. Kovalev

Ural Federal University

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg

G. V. Zyryanov

Ural Federal University; I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620219, Yekaterinburg

O. N. Chupakhin

Ural Federal University; I.Ya. Postovsky Institute of Organic Synthesis of the Ural Branch of the Russian Academy of Sciences

Email: igor.nikonov.ekb@gmail.com
Russian, 620002, Yekaterinburg; Russian, 620219, Yekaterinburg

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Copyright (c) 2023 А.П. Криночкин, А. Раммохан, Д.С. Копчук, И.Л. Никонов, Е.С. Старновская, Э.Р. Шарафиева, И.С. Ковалёв, Г.В. Зырянов, О.Н. Чупахин