Kinetics of Thermal Decomposition of N-Propargil Derivatives of 7H-Difurazanofuxanoazepine and 7H-Trifurasanoazepine
- Authors: Kazakov A.I.1, Lempert D.B.1, Nabatova A.V.1, Ignatieva E.L.1, Dashko D.V.2, Raznoschikov V.V.1, Yanovskiy L.S.1,3
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Affiliations:
- Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
- Tekhnolog Special Design and Technological Bureau
- Moscow Energetic Institute
- Issue: Vol 43, No 3 (2024)
- Pages: 47-54
- Section: Kinetics and mechanism of chemical reactions, catalysis
- URL: https://cijournal.ru/0207-401X/article/view/674972
- DOI: https://doi.org/10.31857/S0207401X24030053
- EDN: https://elibrary.ru/VGHIRS
- ID: 674972
Cite item
Abstract
The thermal stability of the propargyl derivatives of 7H-difurazanofuroxanoazepine and 7H-trifurazanoazepine in isothermal and non-isothermal modes has been studied. Formal kinetic regularities of decomposition and temperature dependences of reaction rate constants are determined. The thermal stability of propargyl, cyanomethyl, allyl and amine derivatives of azepines is compared.
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About the authors
A. I. Kazakov
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
D. B. Lempert
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
A. V. Nabatova
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
E. L. Ignatieva
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
D. V. Dashko
Tekhnolog Special Design and Technological Bureau
Email: akazakov@icp.ac.ru
Russian Federation, Saint Petersburg
V. V. Raznoschikov
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka
L. S. Yanovskiy
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences; Moscow Energetic Institute
Email: akazakov@icp.ac.ru
Russian Federation, Chernogolovka; Moscow
References
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