Phase formation and optical properties of vanadium-doped aluminum oxynitride
- Authors: Ishchenko A.V.1, Akhmadullin N.S.2, Leonidov I.I.3, Sirotinkin V.P.2, Weinstein I.A.1,4, Kargin Y.F.2
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Affiliations:
- Ural Federal University named after the first President of Russia B.N. Yeltsin
- Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
- Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
- Institute of Metallurgy, Ural Branch, Russian Academy of Sciences
- Issue: Vol 70, No 4 (2025)
- Pages: 485-494
- Section: СИНТЕЗ И СВОЙСТВА НЕОРГАНИЧЕСКИХ СОЕДИНЕНИЙ
- URL: https://cijournal.ru/0044-457X/article/view/686938
- DOI: https://doi.org/10.31857/S0044457X25040012
- EDN: https://elibrary.ru/ATAPRG
- ID: 686938
Cite item
Abstract
The phase formation, morphology, and optical properties of aluminum oxynitride (Al5O6N) doped with vanadium ions were studied in the concentration range of 0.01–5.0 at. % (relative to aluminum). All samples were obtained by calcining mixtures of Al2O3, AlN, and V2O5 at a temperature of 1750°C in a nitrogen flow. The resulting materials were predominantly single-phase γ-AlON with minor impurities of aluminum nitride, as well as VC, VN, VO, or their solid solutions, for vanadium concentrations of ≥0.1 at. %. In AlON:V, the band gap (Eg) ranges from 5.82 to 5.94 eV, depending on the vanadium concentration. The luminescence of AlON:V is attributed to intrinsic defects and impurity luminescence centers. The presence of vanadium in AlON results in an increase in the optical absorption and a decrease in the intensity of intrinsic luminescence, which is caused by the formation of vanadium-containing impurity phases.
Full Text

About the authors
A. V. Ishchenko
Ural Federal University named after the first President of Russia B.N. Yeltsin
Author for correspondence.
Email: a-v-i@mail.ru
Russian Federation, Mira str., 19, Yekaterinburg, 620002
N. S. Akhmadullin
Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Email: a-v-i@mail.ru
Russian Federation, Leninsky Prospekt, 49, Moscow, 119334
I. I. Leonidov
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences
Email: a-v-i@mail.ru
Russian Federation, Pervomaiskaya str., 91, Yekaterinburg, 620077
V. P. Sirotinkin
Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Email: a-v-i@mail.ru
Russian Federation, Leninsky Prospekt, 49, Moscow, 119334
I. A. Weinstein
Ural Federal University named after the first President of Russia B.N. Yeltsin; Institute of Metallurgy, Ural Branch, Russian Academy of Sciences
Email: a-v-i@mail.ru
Russian Federation, Mira str., 19, Yekaterinburg, 620002; Amundsen str., 101, Yekaterinburg, 620016
Yu. F. Kargin
Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences
Email: a-v-i@mail.ru
Russian Federation, Leninsky Prospekt, 49, Moscow, 119334
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