Control of the Wetting Ability of a Material by Local Vibration on the Interfacial Layer

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Abstract

The possibility of controlling the wetting ability of a material synthesized in the interfacial layer of a heterogeneous liquid/liquid system by local vibration has been shown. The influence of the nature of the organic acid, metal and solvent on the contact angle of the interfacial layer material adhering to various substrates was studied. It has been established that with local vibration, a material with a more ordered structure, with higher roughness and lower water content, and, as a consequence, with a higher contact angle, is synthesized. On the studied substrates, hydrophobic coatings with contact angles of 100–163° were obtained, which retained their water-repellent properties under atmospheric conditions for a long time.

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About the authors

E. N. Golubina

Новомосковский институт (филиал) Российского химико-технологического университета имени Д.И. Менделеева

Author for correspondence.
Email: Elena-Golubina@mail.ru
Russian Federation, Новомосковск

N. F. Kizim

Новомосковский институт (филиал) Российского химико-технологического университета имени Д.И. Менделеева

Email: Elena-Golubina@mail.ru
Russian Federation, Новомосковск

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2. Fig. 1. Dependence of the edge angle of the material transferred to the glass plate and the change in the shape of the water drop on the synthesis time in the system 0.10 M aqueous solution of YbCl3 / 0.05 M stearic acid solution in chloroform when a local oscillating influence is applied to the system (1) and in its absence (2). Resonance frequency 5.1 kHz

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3. Fig. 2. Surface topography of the material surface of interfacial formations based on ytterbium stearate (a, b) or di-(2-ethylhexyl) ytterbium phosphate (c, d) transferred to a glass plate, when mechanical influence is applied to the system (b, d) and in its absence (a, c). The system is 0.10 M aqueous solution of YbCl3 / 0.05 M solution of stearic acid or D2EGFC in heptane. Resonance frequency 6.6 kHz

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4. Fig. 3. SEM images of the material of interfacial formations based on di-(2-ethylhexyl) ytterbium phosphate synthesised under imposed mechanical vibrations (b) and their absence (a). The system is 0.10 M aqueous solution of YbCl3 / 0.05 M solution of D2EGPC in heptane. Resonance frequency 6.6 kHz

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5. Fig. 4. Photographic images of the interfacial material based on di-(2-ethylhexyl) neodymium phosphate adhered to a glass plate, synthesised by imposing local vibrational action on the system (b) and its absence (a). The system is 0.10 M aqueous solution of NdCl3 / 0.05 M solution of D2EGPC in heptane. Resonance frequency 6.6 kHz

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6. Fig. 5. Dependence of the edge angle of the material transferred to the glass plate on the frequency of vibrocell vibrations during its interfacial synthesis in the system 0.10 M aqueous solution of HoCl3 / 0.05 M solution of stearic acid in chloroform (1), heptane (2), decane (3)

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7. Fig. 6. Variation of the edge angle of aluminium alloy modified with interfacial formation material based on di-(2-ethylhexyl) phosphates: zinc (1), praseodymium (2), holmium (3), stearates: zinc (4), praseodymium (5), holmium (6) from time. System 0.10 M aqueous solution of metal chloride / 0.05 M solution of stearic acid or D2EGFC in heptane

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