Solid Solutions of Complex Hydrosulfates K9H7(SO4)8·H2O–Rb9H7(SO4)8·H2O

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

Crystals of a series of solid solutions (KxRb1–x)9H7(SO4)8·H2O have been studied, and the extreme member of the series Rb9H7(SO4)8·H2O apparently does not exist under normal conditions. Solid solutions are limited by the composition x = 0.19, which corresponds to 81% rubidium content in the cationic composition. The lattice parameters of solid solutions have been determined, thermal properties and dehydration processes of crystallization water for both single-crystal and polycrystalline samples have been studied. The conductivity of samples with the maximum rubidium content has been investigated. It has been shown that the mechanism of occurrence of the state with high conductivity in solid solutions is similar to that in K9H7(SO4)8·H2O and is related to the dehydration process and stabilization of the dehydrated structure.

作者简介

I. Timakov

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

编辑信件的主要联系方式.
Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

V. Komornikov

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

E. Selezneva

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

V. Manomenova

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

E. Rudneva

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

O. Iliina

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

S. Baskakova

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

V. Grebenev

Shubnikov Institute of Crystallography, Kurchatov Complex of Crystallography and Photonics, National Research Centre “Kurchatov Institute”

Email: vadim_grebenev@mail.ru
俄罗斯联邦, Moscow, 119333

参考

  1. Baranov A.I. // Crystallogr. Rep. 2023. V. 48. № 6. P. 1012. https://doi.org/10.1134/1.1627443
  2. Kreuer K.D. // Solid State Ionics. 1997. V. 94. P. 55. https://doi.org/10.1016/S0167-2738(96)00608-X
  3. Haile S.M., Chisholm C.R.I., Sasaki K., Boysen D.A., Uda T. // Faraday Discussions. 2007. V. 134. P. 17. https://doi.org/10.1039/b604311a
  4. Макарова И.П. // Физика твердого тела. 2015. Т. 57. № 3. С. 432. http://journals.ioffe.ru/articles/viewPDF/41498
  5. Haile S.M., Boysen D.A., Chisholm, C.R.I., Merle R.B. // Nature. 2001. V. 410. P. 910. https://doi.org/10.1038/35073536
  6. Dang D., Zhao B., Chen D., Yoo S., Lai S.Y., Doyle B., Dai S., Chen Y., Qu C., Zhang L., Liao S., Liu M. // J. Power Sources. 2017. V. 359. P. 1. https://doi.org/10.1016/j.jpowsour.2017.05.023
  7. Bagryantseva I.N., Ponomareva V.G., Lazareva N.P. // Solid State Ionics. 2019. V. 329. P. 61. https://doi.org/10.1016/j.ssi.2018.11.010
  8. Коморников В.А., Тимаков И.С., Зайнуллин О.Б., Гребенев В.В., Макарова И.П., Селезнева Е.В. // Кристаллография. 2018. Т. 63. № 6. С. 967. https://doi.org/10.1134/S0023476118060188
  9. Komornikov V.A., Timakov I.S., Makarova I.P., Selezneva E.V., Grebenev V.V., Zainullin O.B. // J. Phys.: Conf. Ser. 2020. V. 1686. P. 012048. https://doi.org/10.1088/1742-6596/1686/1/012048
  10. Timakov I.S., Komornikov V.A., Grebenev V.V. // Chem. Phys. 2022. V. 563. P. 111680. https://doi.org/10.1016/j.chemphys.2022.111680
  11. Коморников В.А., Гребенев В.В., Тимаков И.С., Ксенофонтов Д.А., Андреев П.В., Макарова И.П., Селезнева Е.В. // Кристаллография. 2019. Т. 64. № 3. С. 447. https://doi.org/10.1134/S0023476119060109
  12. Тимаков И.С., Гребенев В.В., Коморников В.А., Зайнуллин О.Б., Макарова И.П., Селезнева Е.В., Кузьмин И.И. // Кристаллография. 2022. Т. 67. № 3. С. 488. https://doi.org/10.31857/S0023476122030225
  13. Cowan L.A., Morcos R.M., Hatada N., Navrotsky A., Haile S.M. // Solid State Ionics. 2008. V. 179. № 9–10. P. 305. https://doi.org/10.1016/j.ssi.2008.02.016
  14. Panithipongwut C., Haile S.M. // Solid State Ionics. 2012. V. 213. P. 53. https://doi.org/10.1016/j.ssi.2011.10.016
  15. Kowalski C.P., Chaijaroen P., Kaewniyom F. // J. Met. Mater. Miner. 2021. V. 31. P. 57. https://doi.org/10.55713/jmmm.v31i1.1008
  16. Selezneva E.V., Makarova I.P., Malyshkina I.A., Gavrilova N.D., Grebenev V.V., Novik V.K., and Komornikov V.A. // Acta Crystallogr. B. 2017. V. 73. № 6. P. 1105. https://doi.org/10.1107/S2052520617012847
  17. Petříček V., Dušek M., Palatinus L. // Z. Krist. 2014. V. 229. P. 345. https://doi.org/10.1515/zkri-2014-1737
  18. Makarova I.P., Chernaya T.S., Grebenev V.V., Dolbinina V.V., Verin I.A., Simonov A.A. // Crystallogr. Rep. 2011. V. 56. № 6. P. 994. https://doi.org/10.1134/S1063774511060174
  19. Baranov A.I., Sinitsyn V.V., Vinnichenko V.Y., Jones D.J., Bonnet B. // Solid State Ionics. 1997. V. 97. P. 153. https://doi.org/10.1016/S0167-2738(97)00061-1
  20. Makarova I., Grebenev V., Dmitricheva E., Dolbinina V., Chernyshov D. // Acta Crystallogr. B. 2014. V. 70. P. 218. https://doi.org/10.1107/S2052520613029892

补充文件

附件文件
动作
1. JATS XML
下载

版权所有 © Russian Academy of Sciences, 2025